The Smart Polymer Materials group led by Prof. CHEN Tao at the Ningbo Institute of Materials Technology and Engineering (NIMTE) of Chinese Academy of Sciences (CAS), has developed a fluorescent organohydrogel which can serve as an effective platform for the encryption and decryption of secret information, in cooperation with researchers at Beihang University. The study was published in Advanced Functional Materials (Adv. Funct. Mater.).

Counterfeiting is a global hot issue that poses severe threats to human health, social economy and even country security. Over the past decades, new anti-counterfeiting materials and corresponding encryption/ decryption technologies, including holograms, watermarks, security codes, and fluorescent patterns, have achieved unprecedented development against counterfeiting.

As an effective approach for anti-counterfeiting, stimuli-responsive fluorescent patterns exhibit dynamic color change upon external stimuli, including heat, irradiation, mechanical force, etc., thus gained much worldwide attention. However, it is still challenging to fabricate intelligent fluorescent patterns with continuous color change, especially under a single stimulus.

By virtue of via a two-step interpenetrating technique, researches at NIMTE developed a fluorescent organohydrogel p(DMA-DEAN)/p(SMA-SPMA) as an anti-counterfeiting material, which consists of a hydrophilic p(DMA-DEAN) network emitting green-yellow fluorescence and a hydrophobic p(SMA-SPMA) network with photochromic capability.

The fabricated heterogeneous organohydrogel shows dynamic fluorescence color change from original green then to yellow and red upon ultraviolet (UV) irradiation via the fluorescence resonance energy transfer (FRET) process, and can even recover to original state in response to visible light.

In addition, the loading and encryption of secret information can be achieved by partially treating organohydrogel with H⁺ solution, due to that the introduction of H⁺ can inhibit the FRET process. During the decryption process, the hidden information exhibits a dynamic fluorescence variation.

The strategy may provide a new idea for the design and development of advanced fluorescent anti-counterfeiting materials with dynamic color change, thus improving the information security.

This work was supported by the National Natural Science Foundation of China (Nos. 51873223, 51773215, 21774138), National Key Research and Development Program of China (No. 2018YFB1105100), China Postdoctoral Science Foundation (Grant Nos. 2020M671828), the Natural Science Foundation of Ningbo (No. 202003N4361), Youth Innovation Promotion Association of Chinese Academy of Sciences (Nos. 2017337, 2019297), and Key Research Program of Frontier Science, Chinese Academy of Sciences (No. QYZDB-SSW-SLH036).

Fig. Encryption and dynamic fluorescent decryption based on the developed organohydrogel (Image by NIMTE)

Contact
LE Xiaoxia
Ningbo Institute of Materials Technology and Engineering
E-mail: lexiaoxia@nimte.ac.cn